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Potassium Fluoride
Crystal:
KFStructure: NaCl
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Lattice formation energy: |
-8.24 eV |
Lattice parameter: |
2.66 Å (2.648 at 0K.) |
Density: |
g/cm3 |
Stiffness constants: in 1011 dynes/cm2, at room temperature:
c11: 7.570 (7.585 at 4K.) (Ref.1)
c12: 1.35 (1.473 at 4K.)
c44: 1.336 (1.293 at 4K.)
Compressibility (in 1011 dynes/cm2): 0.292 ??
Poisson ratio:
Debye temperature: 327 or 335 K
Melting temperature: K
Phonon spectrum discussed by:
W. Burher, Lattice dynamics of Potassium Fluoride Phys. Stat. Sol. 41, 789 (1970)
Transverse optic phonon T0 (k=0): 190 or 201.5 cm-1
Longitudinal optic phonon L0 (k=0): cm-1
Gruneissen constant:
Ratio e*/e:
Photoelastic constants:
p11:
p12:
p44:
Band gap:
direct: eV. at K
indirect: eV. at ° K
Plasmon energy: 17.5 eV. (Ref.2)
Exciton energy:
10.6 eV. (Ref.2)
9.58 eV. (Ref.3)
Valence band width: 3.70 eV.
Band structure discussed by:
Static dielectric constant: 6.05 or 5.11
Optic dielectric constant: 1.85 or 1.86
Electron mobility:
Hole mobility:
Polaron coupling constant:
Effective mass:
conduction band:
valence band:
Electron affinity: ( in eV., from bottom of conduction band under vacuum)
0.1 (Ref.3)
4.14, by Mott-Gurney (Ref.4)
Spin-orbit coupling: ( valence band)
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References:
1. Physics Abstracts, 71, No.2056
2. Journal de physique et le Radium, 28 (1981)
3. W.B. Fowler, "Physics of Color Centers", New York: Academic Press (1968)
4. N.F. Mott & R.W. Gurney, "Electronic processes in Ionic crystals", 2nd. Edition (1950)
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