UCL Mathematical & Physical Sciences


Analysis: Sulfuric acid - the resource crisis that could stifle green tech & threaten food security

24 August 2022

Writing in The Conversation, Professor Mark Maslin (UCL Geography) and Dr Simon Day (UCL Institute for Risk & Disaster Reduction) highlight how sulfur, a fossil fuel waste product, is a vital industrial chemical and that the shift to renewable energy could affect its supply.

Credit: kongxinzhu via iStock

Without sulfur in the form of sulfuric acid, industries would struggle to produce the phosphorus fertilisers that raise farm yields or extract the essential metals used in everything from solar panels to electric car batteries.

Yet a problem looms, which has gone largely unnoticed. More than 80% of the global sulfur supply is a waste product, extracted from fossil fuels like oil and natural gas (which typically contain between 1% and 3% sulfur by weight) to reduce emissions of sulfur dioxide, the gas that causes acid rain.

Eliminating fossil fuels to rein in climate change will slash the annual supply of sulfuric acid just as demand is increasing. The world already uses over 246 million tonnes of sulfuric acid annually. Rapid growth in the green economy and intensive agriculture could see demand rise to over 400 million tonnes by 2040.

According to our latest study, a rapid reduction in fossil fuel use required to achieve net zero emissions by 2050 could create a shortfall of sulfuric acid as large as 320 million tonnes by 2040, or 130% of present day production.

Sulfuric acid prices would rise, stoking competition in which more profitable green technology industries are likely to outbid fertiliser producers. This would increase the cost of food production and make food more expensive for consumers, especially in developing countries where farmers are least able to afford the higher costs.

Sulfur is found in a wide range of products, including tyres, sulfur fertiliser, paper, soap and detergent. But its most important application is in industrial chemistry, decomposing a wide range of materials.

The rapidly expanding use of low-carbon technologies, such as high-performance batteries, light-weight motors for vehicles, and solar panels, will significantly increase mining of mineral deposits, particularly laterite ores that are increasingly important sources of cobalt and nickel. Cobalt demand could increase by 460%, nickel by 99%, and neodymium by 37% by 2050. All of these are currently extracted using large quantities of sulfuric acid.

At the same time, projected population growth and dietary trends will also drive an increase in demand for sulfuric acid from its single most important consumer: the phosphate fertiliser production industry.

The US Geological Survey estimates that there is an almost limitless supply of sulfate minerals in evaporites (rocks laid down by the natural evaporation of shallow, salty seas or lakes) and large resources of iron sulfides and elemental sulfur in volcanic deposits, but accessing these would require expanding mining and mineral processing.

Converting sulfates to sulfur using current methods consumes a lot of energy and emits a lot of carbon. Sulfur mining and sulfide ore processing can pollute the air, soil and water, acidifying surface pools and aquifers and emitting toxins including arsenic, thallium and mercury. And there are always human rights issues associated with intensive mining.

In addition to finding new, non-fossil fuel sources of sulfur, demand for sulfur could be reduced by recycling and alternative industrial technologies that avoid intensive use of sulfuric acid.

Recycling phosphate from sewage and turning it into fertiliser would reduce the need for sulfuric acid to process phosphate rock for fertilisers. This would also help to address concerns that, in the long term, the world will run out of phosphate rock. It would also reduce the amount of phosphorus entering freshwater and coastal habitats, which causes massive algal blooms that can suffocate other plants and fish.

Recycling more lithium batteries from electric vehicles could also help. Developing new batteries and motors that rely less on rare metals would reduce demand for sulfuric acid to extract metals from their ores.

Wasting less renewable energy (such as solar and wind) and storing more of it without the use of batteries that need these metals would cut sulfuric acid demand at the same time as it cuts demand for fossil fuels and speeds up decarbonisation. In the future, it may also be possible to produce large quantities of sulfur from sulfates by culturing certain bacteria.

By anticipating future sulfur shortages, national and international policies can manage future demand, increase recycling and develop alternative, cheap supplies which have minimal environmental and social costs.

This article was originally published in The Conversation on 24 August 2022. 



  • Credit: kongxinzhu via iStock