prof franco cacialli
- Prof Franco Cacialli
- Ex: 34467
- Professor of Physics
- Dept of Physics & Astronomy
- Faculty of Maths & Physical Sciences
My research focuses on the study of the optical and electrical properties of organic (carbon-based) and printable semiconductors for optoelectronics and photonics. Research activities in my group span from the study of devices such as light-emitting diodes (LEDs), photovoltaic diodes (PVDs), field-effect transistors (FETs), lasers and sensors, to the investigation of supramolecular architectures for the control of the relevant solid-state properties of conjugated semiconductors. Over the years we have developed a keen interest in the engineering of the electrode-semiconductors interfaces, also with the help of non-invasive optical techniques such as electroabsorption spectroscopy. For example we were first to report an estimate of the work function of the hole-injection layer based on poly(3,4-ethylene dioxythiophene) doped with poly(styrene sulfonate) (PEDOT:PSS) within finished devices, and to correlate this with enhanced device performance in organic LEDs. I also have a strong interest in a variety of high-resolution microscopic techniques and their application to nanopatterning, e.g. by means of the scanning near-field optical microscope (SNOM) and of the Scanning Thermal Microscope (SThM). Very recent interests include stretchable electronics, graphene and derivatives, and low-gap printable materials for emission/absorption in the near-infrared region of the electromagnetic spectrum. This is of interest to both biomedical applications (because of the semitransparency window of biological tissue in the window 700-1000 nm) and to photovoltaics (for the potential to extend the absorption of solar energy to such spectral regions).
- Organic Semiconductors
Neutron Radiation Tolerance of Two Benchmark Thiophene-Based Conjugated Polymers: the Importance of Crystallinity for Organic Avionics.
Triazolobenzothiadiazole-Based Copolymers for Polymer Light-Emitting Diodes: Pure Near-Infrared Emission via Optimized Energy and Charge Transfer
Modifying the Size of Ultrasound-Induced Liquid-Phase Exfoliated Graphene: From Nanosheets to Nanodots.
Increased luminescence efficiency by synergistic exploitation of lipo/hydrophilic co-solvency and supramolecular design
Traceable atomic force microscopy of high-quality solvent-free crystals of [6,6]-phenyl-C-61-butyric acid methyl ester
Luminescent Neutral Cu(I) Complexes: Synthesis, Characterization and Application in Solution-Processed OLED
1994PhDDoctor of PhilosophyUniversita degli Studi di Pisa
1990LAULaureaUniversita degli Studi di Pisa
Franco Cacialli graduated
(cum Laude) from the University of Pisa, and after post-doctoral work at
Cambridge, has been a Royal Society University Research Fellow (1996-2004) at
Cambridge and University College London (UCL), before being promoted to Reader
(2003) and Professor of Physics (2005) in the Department of Physics and
Astronomy and the London Centre for Nanotechnology (LCN,
http://www.london-nano.com/). His research focuses on organic semiconductors
(OS) properties and device applications (http://www.cmmp.ucl.ac.uk/~fc/OS/). Franco has used scanning near-field optical
microscopy (SNOM) and scanning thermal probes for both investigation and
manufacturing of OS nanostructures. A Fellow of the Institute of Physics
(FinstP), a former member of the Advisory Board of "Materials Today"
and of the Journal of Physics C: Condensed Matter, and a current member of
EPSRC Peer Review College, he (co)authored over 200 publications and 6 patents.
Franco has coordinated an 11-partner Marie-Curie
Research Training Network (RTN) dedicated to investigation of threaded
molecular wires (www.threadmill.eu) and
co-edited (with P Samorì – Strasbourg) the book “Functional Supramolecular
Architectures” (Wiley – 2010). Franco
has been elected to a Fellowship of the American Physical Society in 2009.
- Conjugated semiconductors
- Electroabsorption Spectroscopy
- Organic Electronics
- Organic Photonics
- Printable Electronics
- Scanning Near-Field Optical Lithography
- Scanning Thermal Microscopy and Lithography
- Stretchable Electronics