DATOC37

prof derek tocher

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Prof
Derek
A
Tocher
Prof Derek Tocher
Ex: 24709
d.a.tocher@ucl.ac.uk
https://iris.ucl.ac.uk/iris/extResource/image/01/DATOC37
1984-10-01

Appointment

ACAPRO
1984-10-01
1
Professor of Inorganic Chemistry
ME
Dept of Chemistry
MPS
Faculty of Maths & Physical Sciences

Joined UCL

1984-10-01

Research Summary

The Tocher group collaborates in the area of X-ray crystallography across a wide range of chemistry, from conformational studies of flexible organic molecules to characterisation of new inorganic and organometallic compounds with potenital applications in catalysis and materials chemistry. Of particular interest is the study of polymorphism, work carried out in conjunction with computational chemists with a view to gaining an full understanding of the factors controlling the crystallization process.

Research Activities

3523
Inorganic/Organometallic Chemistry
3522
Organic Chemistry
3521
Polymorphism

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UCL CENTRE FOR MATERIALS RESEARCH

prof derek tocher

Research Summary

Synthesis, AACVD and X-ray crystallographic structures of group 13 monoalkoxometallanes

Metalla-macro-tricyclic cryptands: anion encapsulation and selective separation of sulfate via in situ crystallization

A facile synthesis of dibenzopyrroloazepinones as tetracyclic allocolchicinoids - an unusual 1,2-phenyl shift

Carbon-hydrogen bond activation of phenyldi(2-thienyl)phosphine at a triosmium cluster centre

A Computationally Inspired Investigation of the Solid Forms of (R)-1-Phenylethylammonium-(S)-2-phenylbutyrate

Cleavage of Ge-S and C-H bonds in the reaction of electron-deficient [Os-3(CO)(8)(mu-H)(mu(3)-Ph2PCH2P(Ph)C6H4)] with Ph3GeSPh: Generation of thiophenol derivatives [Os-3(CO)(8)(mu-H)(mu-SPh)(mu-dppm)] and [Os-3(CO)(7)(mu-H)(mu-SPh)(mu(3)-SC6H4)(mu-dppm)]

Synthesis, structure and reactivity of tetranuclear square-type complexes of rhenium and manganese bearing pyrimidine-2-thiolate (pymS) ligands: versatile and efficient precursors for mono- and polynuclear compounds containing M(CO)(3) (M = Re, Mn) fragments

Probing weak non-covalent interactions in solution and solid states with designed molecules

A facile synthesis of pyrrolo-(di)-benzazocinones via an intramolecular N-acyliminium ion cyclisation (vol 7, pg 167, 2009)

Reactivity of the triruthenium ortho-metalated cluster [Ru-3(CO)(9){mu(3)- eta(1), kappa(1),kappa(2)-PhP( C6H4) CH2PPh}] with tri(2-thienyl) phosphine and tri( 2-furyl) phosphine: Formation of 1,3-diphenyl-2,3-dihydro-1H-1,3-benzodiphosphine complexes via phosphorus-carbon bond formation